Fremont Brewer wrote: Later on down the road, I may try to split it up between mash water and boil additions.
Not much point in doing that. If you want to acidify the sparge water (shouldn't be necessary if you are building from RO as you won't be building water with high alkalinity) then you can add some acid at sparge time. If you want to lower kettle pH that is usually done by adding the acid to the kettle.
Fremont Brewer wrote: My question is this: For right now, when treating the entire water, do I base my additions on the pre-brew water total, 10 Gallons? Or, do I base my additions on the final volume amount of 6 gallons?
I guess it depends on how you want to procede but I have always just treated the water volume for the entire brew day i.e. mash, infusion, decoction thinning, kettle makeup and hops sparge water are all the same.
You will not (or should not) add anything to the brewing water (chalk) which does not dissolve in it so you can add everythinhg to the HLT without concern in that regard. In the exceptional case where you might wish to emulate carbonaceous water exactly (this is a big pain and involves sparging with CO2 for hours and hours) you might add chalk to the HLT, do the CO2 thing and wind up with an HLT full of water with the same amount of calcium bicarbonate in it as say Burton but as soon as you apply heat the CO2 will escape and the chalk precipitate. This is exactly what would happen if they used an HLT in Burton (which they well may have done). So you would see what the Burton brewer would see but the water would be missing most of the bicarbonate you went to so much trouble to prepare. This is why you don't add chalk to brewing water.