Tue Dec 16, 2008 12:56 pm
I need to listen to that episode, so take this with a grain of salt.
After many years of chemistry, here is my take. The low pH of StarSan will precipitate calcium bicarbonate (or other bicarbonates) out of the water. If you have hard water you will notice that new StarSan gets cloudy right away. But if you leave it for a few weeks, that will settle out. Basically it is just gravity acting like a really slow centrifuge. As it settles out I just decant the clear StarSan off the precipitate and replenish the volume after I lose a significant amount. It is just a pH-dependent way of softening the water and happens with bicarb at low pH.
I personally go by pH. In his Session interview, as well as through a few personal emails (he is really good about answering) Jon said that as long as the pH is 3 or below, StarSan is effective. I measure the pH every time and don't worry about the cloudy precipitate. I have not had an infection ever in my days using StarSan (3+ years and over 200 batches).
Now, with that said, I will go listen to the interview and see if I am just a total buffoon that has been really lucky.